Publications

2017 top

Dynamics of poly(vinyl methyl ketone) thin films studied by local dielectric spectroscopy
R. Casalini, M. Labardi, and C.M. Roland J. Phys. Chem.146, 203315 (2017).

Role of structure in the α and β dynamics of a simple glass-forming liquid
D. Fragiadakis and C.M. Roland Phys. Rev. E 95, 022607 (2017).

2016 top

Deformation of polyurea: Where does the energy go?
P.H. Mott, C.B. Giller, D. Fragiadakis, D.A. Rosenberg and C.M. Roland Polymer 105, 227 (2016).

Elastomer-Metal Laminate Armor
R.M. Gamache, C.B. Giller, G. Montella, D. Fragiadakis, and C.M. Roland Materials and Design 111, 362 (2016).

Density Scaling and Decoupling in o-Terphenyl, Salol, and Dibutylphthalate
R. Casalini, S.S. Bair, and C.M. Roland J. Chem. Phys. 145, 064502 (2016).

Coating/Substrate Interaction in Elastomer-Steel Bilayer Armor
C.B. Giller, R.M. Gamache, K.J. Wahl, A.P. Saab, and C.M. Roland J. Composite Materials 50, 2853 (2016).

Dynamics of the strong metallic glass Zn38Mg12Ca32Yb18
J.C. Qiao, R. Casalini, J.M. Pelletier, and Y. Yao J. Non-Cryst. Solids 447, 85 (2016).

Local and Global Dynamics in Polypropylene Glycol/Silica Composites
R. Casalini and C.M. Roland Macromolecules 49, 3919 (2016).

Interplay between Core and Interfacial Mobility and Its Impact on the Measured Glass Transition: Dielectric and Calorimetric Studies
M. Tarnacka, E. Kaminska, K. Kaminski, C.M. Roland, and M. Paluch J. Phys. Chem. C 120, 7373 (2016).

Electrical and Dielectric Properties of Rubber
C.M. Roland Rubber Chemistry & Technology 89, 32 (2016).

Segmental Dynamics and the Correlation Length in Nanoconfined PMMA
R. Casalini, L. Zhu, E. Baer, and C.M. Roland Polymer 88, 133 (2016).

The 'Anomalous' Dynamics of Decahydroisoquinoline Revisited
R. Casalini and C.M. Roland J. Chem. Phys. 144, 024502 (2016).

Reinforcement of Elastomers
C.M. Roland in Materials Science & Materials Engineering (S. Hashmi, Ed.) Elsevier (2016).

2015 top

Extended Model for the Interaction of Dielectric Thin Films with an Electrostatic Force Microscope Probe
M. Labardi, J. Barsotti, D. Prevosto, S. Capaccioli, C.M. Roland, R. Casalini J. Appl. Phys. 118, 224104 (2015).

The Effect of Nanoclay on the Rheology and Dynamics of Polychlorinated Biphenyl
D. Roy, R. Casalini, C.M. Roland Soft Matter 11, 9379 (2015).

The Rheology and Gelation of Bidisperse 1,4-Polybutadiene
D. Roy, C.B. Giller, T.E. Hogan, C.M. Roland Polymer 81, 1117 (2015).

Underwater Sound Transmission through Arrays of Disk Cavities in a Soft Elastic Medium
D.C. Calvo, A.L. Thangawng, C.N. Layman Jr., R. Casalini, S.F. Othman J. Acoust. Soc. Am.138, 2537 (2015).

Measuring the Blast and Ballistic Performance of Armor
C.M. Roland, R.M. Gamache NRL Formal Report (NRL/FR/6126-15-10,284, 2015).

Effect of Interface Interaction on the Segmental Dynamics of Poly(vinyl acetate) Investigated by Local Dielectric Spectroscopy
R. Casalini, D. Prevosto, M. Labardi, C.M. Roland ACS MacroLetters 4, 1022 (2015).

Rotational Dynamics of Simple Asymmetric Molecules
D. Fragiadakis, C.M. Roland Phys. Rev. E 91, 022310 (2015).

Dynamic Correlation Length Scales under Isochronal Conditions
R. Casalini, D. Fragiadakis, C.M. Roland J. Chem. Phys. 142, 064504 (2015).

Thermoplastic Elastomers of Alloocimene and Isobutylene Triblock Copolymers
J.H. Roh, D. Roy, W.K. Lee, A.L. Gergely, J.E. Puskas, C.M. Roland Polymer 56, 280 (2015).

Interpenetrating Polymer Networks - Structure and Mechanical Behavior
C.M. Roland in Encyclopedia of Polymeric Nanomaterials (Springer, 2015).

Impact-Resistant Elastomeric Coatings,
C.M. Roland, C.G. Giller in Elastomeric Polymers with High Rate Sensitivity (Elsevier, 2015).

Dielectric Relaxation Spectroscopy,
C.M. Roland in Impedance Spectroscopy (Wiley-Interscience), to be published.

Main (α) Relaxation and Excess Wing in Zr50Cu40Al10 Bulk Metallic Glass Investigated by Mechanical Spectroscopy
J.C. Qiao, R. Casalini, J.M. Pelletier J. Non-Cryst. Solids 407, 106 (2015).

2014 top

Effect of Physical Aging on Johari-Goldstein Relaxation in La-based Bulk Metallic Glass
J.C. Qiao, R. Casalini, J.M. Pelletier J. Chem. Phys.141, 104510 (2014).

Effect of Regioisomerism on the Local Dynamics of Polychlorostyrene
R. Casalini, C.M. Roland Macromolecules 47, 4087 (2014).

Determination of the Thermodynamic Scaling Exponent from Static, Ambient-Pressure Quantities
R. Casalini, C.M. Roland Phys. Rev. Lett.113, 085701 (2014).

Ion and Chain Mobility in a Tetrazole Proton-Conducting Polymer
R. Casalini, B.L. Chaloux, C.M. Roland, H.L. Ricks-Laskoski J. Phys. Chem. C 118, 6661 (2014).

Characteristics of the Structural and Johari-Goldstein Relaxations in Pd-Based Metallic Glass-Forming Liquids
J. Qiao, R. Casalini, J.-M. Pelletier, H. Kato J. Phys. Chem. B 118, 3720 (2014).

Phase Behavior and Dynamics of a Cholesteric Liquid Crystal
D. Roy, D. Fragiadakis, C.M. Roland, R. Dabrowski, J. Dziaduszek, S. Urban J. Chem. Phys. 140, 074502 (2014).

Volumetric Study of n-Octyloxy-cyanobiphenyl (8OCB)
C.M. Roland, D. Fragiadakis, D. Roy, S. Urban Liquid Crystals 41, 9 (2014).

Influence of Liquid Media on Lifetime Predictions of Nitrile Rubber,
G.S. Buckley, C.M. Roland J. Appl. Polym. Sci. 131, 40296 (2014).

2013 top

Reentanglement Kinetics in Polyisobutylene,
D. Roy, C.M. Roland Macromolecules 46, 9403 (2013).

Relaxation of Bulk Metallic Glasses Studied by Mechanical Spectroscopy,
J. Qiao, J.-M. Pelletier, R. Casalini J. Phys. Chem. B 117, 13658 (2013).

Investigation of the Role of the Acceptor Molecule in Bulk Heterojunction Photovoltaic Cells Using Impedance Spectroscopy,
R. Casalini, S.W. Tsang, J.J. Deininger, F.A. Arroyave, J.R. Reynolds, F. So J. Phys. Chem. C 117, 13798 (2013).

Effect of Binding to Carbon Black on the Dynamics of 1,4-Polybutadiene,
J.H. Roh, M. Tyagi, T. E. Hogan, C.M. Roland J. Chemical Physics 139, 134905 (2013).

Space-Dependent Dynamics in 1,4-Polybutadiene Nanocomposite,
J.H. Roh, M. Tyagi, T. E. Hogan, C.M. Roland Macromolecules 46, 6667 (2013).

Unconventional Rubber Networks: Circumventing the Compromise between Stiffness and Strength,
C.M. Roland Rubber Chemistry & Technology 86, 531 (2013).

Characteristics of the Johari-Goldstein Process in Rigid Asymmetric Molecules,
D. Fragiadakis, C.M. Roland Phys. Rev. E 88, 042307 (2013).

Thermorheological Complexity in Polymers and the Problem of the Glass Transition,
K.L. Ngai, C.M. Roland J. Chem. Phys. 139, 036101 (2013).

Structure Characterization in the Science and Technology of Elastomers,
C.M. Roland in The Science and Technology of Rubber (Elsevier) 2013.

Rheological Behavior and Processing of Unvulcanized Rubber,
C.M. Roland in The Science and Technology of Rubber (Elsevier) 2013.

Strength Enhancement in Miscible Blends of Butyl Rubber and Polyisobutylene,
C.B. Giller, C.M. Roland Macromolecules 46, 2818 (2013).

Immiscible Rubber Blends,
C.M. Roland in Advances in Elastomers (Springer-Verlag) 2013.

Failure of Classical Elasticity in Auxetic Foams,
J.H. Roh, C.B. Giller, P.H. Mott, C.M. Roland AIP Advances 3, 042126 (2013).

Are Polar Liquids Less Simple?,
D. Fragiadakis, C.M. Roland J. Chem. Phys. 138, 12A502 (2013).

Factors Influencing the Ballistic Impact Resistance of Elastomer-Coated Metal Substrates,
C.M. Roland, D. Fragiadakis, R.M. Gamache, R. Casalini Philos. Mag. 93, 468 (2013).

Limits to Poisson's Ratio in Isotropic Materials - General Result for Arbitrary Deformation,
P.H. Mott and C.M. Roland Physica Scripta 87, 055404 (2013).

2012 top

Neutron Scattering in the Analysis of Polymers,
C.M. Roland Encyclopedia of Analytical Chemistry (John Wiley & Sons) 2012.

Glass Transition in Rubbery Materials,
C.M. Roland Rubber Chemistry & Technology 85, 313 (2012).

Molecular Dynamics Simulations of the Johari-Goldstein Relaxation in a Molecular Liquid,
D. Fragiadakis and C.M. Roland Phys. Rev. E 86, 020501 (2012).

Volumetric, Dielectric, Calorimetric and X-ray Studies of Smectogenic 10PBO8 at Atmospheric and Elevated Pressures,,
C.M. Roland, D. Fragiadakis, R. Bogoslovov, S. Urban, R. Dabrowski, M. Tykarska, N. Osiecka, and J. Czub Liquid Crystals 39, 993 (2012).

Tracking of Proton Transfer Reaction in Supercooled RNA Nucleoside,
Z. Wojnarowska, M. Paluch, P. Wlodarczyk, M. Dulski, R. Wrzalik, and C.M. Roland J. Phys. Chem. Lett. 3, 2288 (2012).

Quantifying the Structural Dynamics of Pharmaceuticals in the Glassy State,
Z. Wojnarowska, C.M. Roland, K. Kolodziejczyk, A. Swiety-Pospiech, K. Grzybowska, and M. Paluch J. Phys. Chem. Lett. 3, 1238 (2012).

Anomalous Electrical Conductivity Behavior at Elevated Pressure in the Protic Ionic Liquid Procainamide Hydrochloride,
Z. Wojnarowksa, C.M. Roland, A. Swiety-Pospiech, K. Grzybowska, M. Paluch Phys. Rev. Lett. 108, 015701 (2012).

Nanofiller Reinforcement of Elastomeric Polyurea,
R. Casalini, R. Bogoslovov, S.B. Qadri, and C.M. Roland Polymer 53, 1282 (2012).

Microstructure and Segmental Dynamics of Polyurea under Uniaxial Deformation,
T. Choi, D. Fragiadakis, C.M. Roland, and J. Runt Macromolecules 45, 3581 (2012).

2011 top

Book: Viscoelastic Behavior of Rubbery Materials (Oxford Univ. Press, 2011) C.M. Roland.

      reviews

      Chapter 1 Introduction

      Chapter 4 Networks

The role of the isothermal bulk modulus in the molecular dynamics of super-cooled liquids,
A.N. Papathanassiou, I. Sakellis, J. Grammatikakis, C.M. Roland J. Chem. Phys. 135, 244508 (2011).

Density-scaling and the Prigogine-Defay ratio in liquids,
R. Casalini, R.F. Gamache, C.M. Roland J. Chem. Phys. 135, 224501 (2011).

Flocculation, reinforcement, and glass transition effects in silica-filled styrene-butadiene rubber,
C.G. Robertson, C.J. Lin, R.B. Bogoslovov, M. Rakaitis, P. Sadhukhan, J.D. Quinn, C.M. Roland Rubber Chem. Tech. 84, 507 (2011).

On the low-frequency peak in the dielectric spectrum of glycerol,
R. Casalini, C.M. Roland J. Chem. Phys. 135, 094502 (2011).

Relaxation Dynamics of Polymethylacrylate at Elevated Pressure,
R. Casalini, D. Fragiadakis, C.M. Roland Macromolecules 44, 6928 (2011).

A Comparison of the Transient Stress-Strain Response of Rubber to Its Linear Dynamic Behavior,
P.H. Mott, J.N. Twigg, C.M. Roland, K.E. Nugent, T.E. Hogan, C.G. Robertson, J. Polym. Sci. Polym. Phys. Ed. 49, 1195 (2011).

Phase Diagram and Dynamics of the Liquid Crystal Isopentylcyanobiphenyl (5*CB),
D. Fragiadakis, S. Urban, M. Massalska-Arodz, R.B. Bogoslovov, J. Czub, C.M. Roland J. Phys. Chem. B 118, 6437 (2011).

Predicting the Density-Scaling Exponent of a Glass-Forming Liquid from Prigogine-Defay Ratio Measurements,
D. Gundermann, U.R. Pedersen, T. Hecksher, N. Bailey, B. Jakobsen, T. Christensen, N.B. Olsen, T.B. Schrøder, D. Fragiadakis, R. Casalini, C.M. Roland, J.P. Dyre, K. Niss Nature Physics 7, 816 (2011).

Strength Enhancement from Heterogeneous Networks of Ethylene-Propylene / Ethylene-Propylene-Diene,
G.S. Buckley; D. Fragiadakis; C.M. Roland Rubber Chem. Tech. 84, 520 (2011).

Aging of a low molecular weight poly(methyl methacrylate),
R. Casalini; C.M. Roland, J. Non-Crystalline Solids 357, 282 (2011).

Heterogeneous slow dynamics and the interaction potential of glass-forming liquids,
D. Coslovich; C.M. Roland, J. Non-Crystalline Solids 357, 397 (2011).

Low Frequency Relaxation in Liquid Crystals in Relation to Structural Relaxation in Glass-Formers,
S. Urban; C.M. Roland, J. Non-Crystalline Solids 357, 740 (2011).

Dynamic Heterogeneity and Density Scaling in 1,4-polyisoprene,
D. Fragiadakis; R. Casalini; R.B. Bogoslovov; C.G. Robertson; C.M. Roland, Macromolecules 44, 1149 (2011). [doi]

Connection between dynamics and thermodynamics of liquids on the melting line,
D. Fragiadakis; C.M. Roland, Phys. Rev. E. 83, 031504 (2011). [doi]

On the density scaling of liquid dynamics,
D. Fragiadakis; C.M. Roland J. Chem. Phys. 134, 044504 (2011). [doi]

2010 top

Correlation of nonexponentiality with dynamic heterogeneity from four-point dynamic susceptibility chi(4)(t) and its approximation chi(T)(t),
C.M. Roland; D. Fragiadakis; D. Coslovich; S. Capaccioli; K.L. Ngai, J. Chem. Phys. 133, 124507 (2010). [doi]

Theoretical Implications of the Elastic Modulus Discontinuity in Rubber Networks,
D.E. Hanson; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 48, 1795 (2010). [doi]

Dielectric and mechanical relaxation in isooctylcyanobiphenyl (8*OCB),
S. Pawlus; M. Mierzwa; M. Paluch; S.J. Rzoska; C.M. Roland, J. Phys.-Condes. Matter 22, 235101 (2010). [doi]

Clarifying the Molecular Weight Dependence of the Segmental Dynamics of Polybutadiene,
R.B. Bogoslovov; T.E. Hogan; C.M. Roland, Macromolecules 43, 2904 (2010). [doi]

Effect of Crosslinking on the Secondary Relaxation in Polyvinylethylene,
R. Casalini; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 48, 582 (2010). [doi]

Elastomer-steel laminate armor,
C.M. Roland; D. Fragiadakis; R.M. Gamache, Compos. Struct. 92, 1059 (2010). [doi]

Segmental dynamics of polyurea: Effect of stoichiometry,
D. Fragiadakis; R. Gamache; R.B. Bogoslovov; C.M. Roland, Polymer 51, 178 (2010). [doi]

2009 top

Structural Arrest and Thermodynamic Scaling in Filler-reinforced Polymers,
C.G. Robertson; R. Bogoslovov; C.M. Roland, Rubber Chem. Technol. 82, 202 (2009).

Limits to Poisson's ratio in isotropic materials,
P.H. Mott; C.M. Roland, Phys. Rev. B 80, 132104 (2009). [doi]

Vagaries of elastomer service life predictions,
C.M. Roland, Plast. Rubber Compos. 38, 349 (2009). [doi]

Density scaling in viscous liquids: From relaxation times to four-point susceptibilities,
D. Coslovich; C.M. Roland, J. Chem. Phys. 131, 151103 (2009). [doi]

Comment on "Resolving the Mystery of the Chain Friction Mechanism in Polymer Liquids",
K.L. Ngai; D.J. Plazek; C.M. Roland, Phys. Rev. Lett. 103, 159801 (2009). [doi]

Density Scaling and Dynamic Correlations in Viscous Liquids,
D. Fragiadakis; R. Casalini; C.M. Roland, J. Phys. Chem. B 113, 13134 (2009). [doi]

Anomalous properties of the local dynamics in polymer glasses,
R. Casalini; C.M. Roland, J. Chem. Phys. 131, 114501 (2009). [doi]

On the pressure dependence of the fragility of glycerol,
S. Pawlus; M. Paluch; J. Ziolo; C.M. Roland, J. Phys.-Condes. Matter 21, 332101 (2009). [doi]

A Theoretical Analysis of Rheodielectric Response of Type-A Polymer Chains,
T. Uneyama; Y. Masubuchi; K. Horio; Y. Matsumiya; H. Watanabe; J.A. Pathak; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 47, 1039 (2009). [doi]

Aging of the Secondary Relaxation to Probe Structural Relaxation in the Glassy State,
R. Casalini; C.M. Roland, Phys. Rev. Lett. 102, 035701 (2009). [doi]

Pressure-energy correlations and thermodynamic scaling in viscous Lennard-Jones liquids,
D. Coslovich; C.M. Roland, J. Chem. Phys. 130, 014508 (2009). [doi]

2008 top

Naval and Space Applications of Rubber,
C.M. Roland in Rubber Technologist's Handbook (Rapra) 2008.

Interaction Potential in Nematogenic 6CHBT,
R.B. Bogoslovov; C.M. Roland; J. Czub; S. Urban, J. Phys. Chem. B 112, 16008 (2008). [doi]

Structure Evolution in a Polyurea Segmented Block Copolymer Because of Mechanical Deformation,
J.A. Pathak; J.N. Twigg; K.E. Nugent; D.L. Ho; E.K. Lin; P.H. Mott; C.G. Robertson; M.K. Vukmir; T.H. Epps; C.M. Roland, Macromolecules 41, 7543 (2008). [doi]

Glass Transition and Interfacial Segmental Dynamics in Polymer-particle Composites,
C.G. Robertson; C.M. Roland, Rubber Chem. Technol. 81, 506 (2008).

A scaling parameter and function for the accurate correlation of viscosity with temperature and pressure across eight orders of magnitude of viscosity,
S. Bair; R. Casalini, J. Tribol.-Trans. ASME 130, 041802 (2008). [doi]

Polyisobutylene: A most unusual polymer,
K. Kunal; M. Paluch; C.M. Roland; J.E. Puskas; Y. Chen; A.P. Sokolov, J. Polym. Sci. Pt. B-Polym. Phys. 46, 1390 (2008). [doi]

Thermodynamic scaling and the characteristic relaxation time at the phase transition of liquid crystals,
C.M. Roland; R.B. Bogoslovov; R. Casalini; A.R. Ellis; S. Bair; S.J. Rzoska; K. Czuprynski; S. Urban, J. Chem. Phys. 128, 224506 (2008). [doi]

On the universality of chain dynamics,
K.L. Ngai; D.J. Plazek; C.M. Roland, Macromolecules 41, 3925 (2008). [doi]

Pressure-induced polymerization of tetraethylene glycol dimethacrylate,
K. Kaminski; M. Paluch; R. Wrzalik; J. Ziolo; R. Bogoslovov; C.M. Roland, J. Polym. Sci. Pol. Chem. 46, 3795 (2008). [doi]

On the pressure evolution of dynamic properties of supercooled liquids,
A. Drozd-Rzoska; S.J. Rzoska; C.M. Roland; A.R. Imre, J. Phys.-Condes. Matter 20, 244103 (2008). [doi]

Pressure-induced polymerization of phenoxyethyl acrylate,
K. Kaminski; R. Wrzalik; M. Paluch; J. Ziolo; C.M. Roland, J. Phys.-Condes. Matter 20, 244121 (2008). [doi]

Guides to solving the glass transition problem,
K.L. Ngai; D. Prevosto; S. Capaccioli; C.M. Roland, J. Phys.-Condes. Matter 20, 244125 (2008). [doi]

The bulk modulus and Poisson's ratio of "incompressible" materials,
P.H. Mott; J.R. Dorgan; C.M. Roland, J. Sound Vibr. 312, 572 (2008). [doi]

Influence of particle size and polymer-filler coupling on viscoelastic glass transition of particle-reinforced polymers,
C.G. Robertson; C.J. Lin; M. Rackaitis; C.M. Roland, Macromolecules 41, 2727 (2008). [doi]

The inflection point in the pressure dependence of viscosity under high pressure: A comprehensive study of the temperature and pressure dependence of the viscosity of propylene carbonate,
R. Casalini; S. Bair, J. Chem. Phys. 128, 084511 (2008). [doi]

Effect of silica nanoparticles on the local segmental dynamics in poly(vinyl acetate),
R.B. Bogoslovov; C.M. Roland; A.R. Ellis; A.M. Randall; C.G. Robertson, Macromolecules 41, 1289 (2008). [doi]

Role of hydrogen bonds in the supercooled dynamics of glass-forming liquids at high pressures,
C.M. Roland; R. Casalini; R. Bergman; J. Mattsson, Phys. Rev. B 77, 012201 (2008). [doi]

Thermodynamic scaling of diffusion in supercooled Lennard-Jones liquids,
D. Coslovich; C.M. Roland, J. Phys. Chem. B 112, 1329 (2008). [doi]

2007 top

The effect of thermodynamic variables on polymer chain dynamics,
C.M. Roland, Curr. Opin. Solid State Mat. Sci. 11, 41 (2007). [doi]

Fragility and the dynamic crossover in lubricants,
S. Bair; C.M. Roland; R. Casalini, Proc. Inst. Mech. Eng. Part J.-J. Eng. Tribol. 221, 801 (2007). [doi]

Isobaric and isochoric properties of glass-formers,
R. Casalini; C.M. Roland, NATO Sci. Series 242, 141 (2007).

Effect of hydrostatic pressure on the viscoelastic response of polyurea,
C.M. Roland; R. Casalini, Polymer 48, 5747 (2007). [doi]

Thermodynamic analysis of the low frequency relaxation time in the smectic A and C phases of a liquid crystal,
S. Urban; C.M. Roland; J. Czub; K. Skrzypek, J. Chem. Phys. 127, 094901 (2007). [doi]

Effect of structural arrest on Poisson's ratio in nanoreinforced elastomers,
C.G. Robertson; R. Bogoslovov; C.M. Roland, Phys. Rev. E 75, 051403 (2007). [doi]

Entropy basis for the thermodynamic scaling of the dynamics of o-terphenyl,
C.M. Roland; R. Casalini, J. Phys.-Condes. Matter 19, 205118 (2007). [doi]

Impact-induced glass transition in elastomeric coatings,
R.B. Bogoslovov; C.M. Roland; R.M. Gamache, Appl. Phys. Lett. 90, 221910 (2007). [doi]

High-speed tensile test instrument,
P.H. Mott; J.N. Twigg; D.F. Roland; H.S. Schrader; J.A. Pathak; C.M. Roland, Rev. Sci. Instrum. 78, 045105 (2007). [doi]

On the glass temperature under extreme pressures,
A. Drozd-Rzoska; S.J. Rzoska; M. Paluch; A.R. Imre; C.M. Roland, J. Chem. Phys. 126, 164504 (2007). [doi]

High strain rate mechanical behavior of polyurea,
C.M. Roland; J.N. Twigg; Y. Vu; P.H. Mott, Polymer 48, 574 (2007). [doi]

Dielectric relaxation of alpha-tocopherol acetate (vitamin E),
K. Kaminski; S. Maslanka; J. Ziolo; M. Paluch; K.J. McGrath; C.M. Roland, Phys. Rev. E 75, 011903 (2007). [doi]

The nearly constant loss, Johari-Goldstein beta-relaxation, and alpha-relaxation of 1,4-polybutadiene,
M.J. Schroeder; K.L. Ngai; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 45, 342 (2007). [doi]

Viscoelastic effects on the free retraction of rubber,
R.B. Bogoslovov; C.M. Roland, J. Appl. Phys. 102, 063531 (2007). [doi]

2006 top

Recovery of shear-modified polybutadiene solutions,
C.M. Roland; C.G. Robertson, Rubber Chem. Technol. 79, 267 (2006).

Mechanical behavior of rubber at high strain rates,
C.M. Roland, Rubber Chem. Technol. 79, 429 (2006).

Scaling of the local dynamics and the intermolecular potential,
C.M. Roland; J.L. Feldman; R. Casalini, J. Non-Cryst. Solids 352, 4895 (2006). [doi]

Isobaric and isochoric properties of decahydroisoquinoline, an extremely fragile glass-former,
R. Casalini; K.J. McGrath; C.M. Roland, J. Non-Cryst. Solids 352, 4905 (2006). [doi]

Volume effects on the glass transition dynamics,
C.M. Roland; K.J. McGrath; R. Casalini, J. Non-Cryst. Solids 352, 4910 (2006). [doi]

Thermodynamic scaling of the viscosity of van der Waals, H-bonded, and ionic liquids,
C.M. Roland; S. Bair; R. Casalini, J. Chem. Phys. 125, 124508 (2006). [doi]

Thermodynamic interpretation of the scaling of the dynamics of supercooled liquids,
R. Casalini; U. Mohanty; C.M. Roland, J. Chem. Phys. 125, 014505 (2006). [doi]

What can we learn by squeezing a liquid?,
R. Casalini; S. Capaccioli; C.M. Roland, J. Phys. Chem. B 110, 11491 (2006). [doi]

Dynamic heterogeneity in poly(vinyl methyl ether)/poly(2-chlorostyrene) blends,
C.M. Roland; K.J. McGrath; R. Casalini, Macromolecules 39, 3581 (2006). [doi]

Enthalpy relaxation and fragility in polychlorinated biphenyls,
C.M. Roland; R. Casalini, J. Therm. Anal. Calorim. 83, 87 (2006).

2005 top

Effect of glass structure on the dynamics of the secondary relaxation in diisobutyl and diisoctyl phthalates,
M. Paluch; S. Pawlus; S. Hensel-Bielowka; K. Kaminski; T. Psurek; S.J. Rzoska; J. Ziolo; C.M. Roland, Phys. Rev. B 72, 224205 (2005) [doi]

The role of density and temperature in the dynamics of polymer blends
C.M. Roland; R. Casalini, Macromolecules 38, 8729 (2005). [doi]

Why liquids are fragile
R. Casalini; C.M. Roland, Phys. Rev. E 72, 031503 (2005). [doi]

Identifying the genuine Johari-Goldstein beta-relaxation by cooling, compressing, and aging small molecular glass-formers,
S. Capaccioli; D. Prevosto; M. Lucchesi; P.A. Rolla; R. Casalini; K.L. Ngai, J. Non-Cryst. Solids 351, 2643 (2005). [doi]

Hydrogen bonding and secondary relaxations in propylene glycol trimer
S. Pawlus; S. Hensel-Bielowka; M. Paluch; R. Casalini; C.M. Roland, Phys. Rev. B 72, 064201 (2005). [doi]

Supercooled dynamics of glass-forming liquids and polymers under hydrostatic pressure
C.M. Roland; S. Hensel-Bielowka; M. Paluch; R. Casalini, Rep. Prog. Phys. 68, 1405 (2005). [doi]

Heterogeneous networks of polyisoprene/polyvinylethylene
J. Wang; C.M. Roland, Polymer 46, 4160 (2005). [doi]

The Payne effect in double network elastomers
J. Wang; G.R. Hamed; K. Umetsu; C.M. Roland, Rubber Chem. Technol. 78, 76 (2005).

Reply to "Comment on 'Correlation between configurational entropy and structural relaxation time in glass-forming liquids' "
D. Prevosto; S. Capaccioli; M. Lucchesi; P.A. Rolla; R. Casalini, Phys. Rev. B 71, 136202 (2005). [doi]

Mode coupling behavior in glass-forming liquid crystalline isopentylcyanobiphenyl
A. Drozd-Rzoska; S.J. Rzoska; M. Paluch; S. Pawlus; J. Ziolo; P.G. Santangelo; C.M. Roland; K. Czuprynski; R. Dabrowski, Phys. Rev. E 71, 011508 (2005). [doi]

Primary and secondary relaxations in bis-5-hydroxypentylphthalate
S. Maslanka; M. Paluch; W.W. Sulkowski; C.M. Roland, J. Chem. Phys. 122, 084511 (2005). [doi]

2004 top

Effect of constraints on electrostriction,
C.M. Roland; J.T. Garrett, Nonlinear Dielectric Phenomena in Complex Liquids (S.J. Rzoska and V. Zheleny, Eds.) Kluwer Acad. Publ. (2004).

Temperature and volume effects on the change of dynamics in propylene carbonate,
S. Pawlus; R. Casalini; C.M. Roland; M. Paluch; S.J. Rzoska; J. Ziolo, Phys. Rev. E 70, 061501 (2004). [doi]

Reentanglement kinetics in sheared polybutadiene solutions,
C.G. Robertson; S. Warren; D.J. Plazek; C.M. Roland, Macromolecules 37, 10018 (2004). [doi]

Naval Applications of Elastomers,
C.M. Roland, Rubber Chem. Technol. 77, 542 (2004).

Observation of chain dynamics in depolarized light scattering spectra of polymers,
Y.F. Ding; V.N. Novikov; A.P. Sokolov; R. Casalini; C.M. Roland, Macromolecules 37, 9273 (2004). [doi]

Effects of the volume and temperature on the global and segmental dynamics in poly(propylene glycol) and 1,4-polyisoprene,
C.M. Roland; M. Paluch; R. Casalini, J. Polym. Sci. Pt. B-Polym. Phys. 42, 4313 (2004). [doi]

Models for the component dynamics in blends and mixtures,
K.L. Ngai; C.M. Roland, Rubber Chem. Technol. 77, 579 (2004).

Modes of molecular motion in low molecular weight polystyrene,
C.M. Roland; K.L. Ngai; D.J. Plazek, Macromolecules 37, 7051 (2004). [doi]

Thermodynamical scaling of the glass transition dynamics,
R. Casalini; C.M. Roland, Phys. Rev. E 69, 062501 (2004). [doi]

The compression of bonded rubber disks,
M.L. Anderson; P.H. Mott; C.M. Roland, Rubber Chem. Technol. 77, 293 (2004).

Filler dispersion in hyperbranched polyisobutylene,
C.M. Roland; C.G. Robertson; L. Nikiel; J.E. Puskas, Rubber Chem. Technol. 77, 372 (2004).

Viscosity at the dynamic crossover in o-terphenyl and salol under high pressure,
R. Casalini; C.M. Roland, Phys. Rev. Lett. 92, 245702 (2004). [doi]

Local segmental relaxation in bidisperse polystyrenes,
C.G. Robertson; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 42, 2604 (2004). [doi]

Effect of large hydrostatic pressure on the dielectric loss spectrum of type-A glass formers,
S. Hensel-Bielowka; S. Pawlus; C.M. Roland; J. Ziolo; M. Paluch, Phys. Rev. E 69, 050501 (2004). [doi]

Adam-Gibbs model for the supercooled dynamics in the ortho-terphenyl ortho-phenylphenol mixture,
C.M. Roland; S. Capaccioli; M. Lucchesi; R. Casalini, J. Chem. Phys. 120, 10640 (2004). [doi]

Effect of the isobaric and isothermal reductions in excess and configurational entropies on glass-forming dynamics,
S. Capaccioli; M. Lucchesi; D. Prevosto; R. Casalini; P. Rolla, Philos. Mag. 84, 1513 (2004). [doi]

Structural and secondary relaxations in supercooled di-n-butyl phthalate and diisobutyl phthalate at elevated pressure,
M. Sekula; S. Pawlus; S. Hensel-Bielowka; J. Ziolo; M. Paluch; C.M. Roland, J. Phys. Chem. B 108, 4997 (2004). [doi]

Determining Rouse relaxation times from the dynamic modulus of entangled polymers,
C.M. Roland; L.A. Archer; P.H. Mott; J. Sanchez-Reyes, J. Rheol. 48, 395 (2004). [doi]

Mechanical and electromechanical properties of vinylidene fluoride terpolymers,
C.M. Roland; J.T. Garrett; R. Casalini; D.F. Roland; P.G. Santangelo; S.B. Qadri, Chem. Mat. 16, 857 (2004). [doi]

2003 top

Effect of temperature and pressure on segmental relaxation in polymethylphenylsiloxane,
S. Pawlus; S.J. Rzoska; J. Ziolo; M. Paluch; C.M. Roland, Rubber Chem. Technol. 76, 1106 (2003).

Pressure effects on the segmental dynamics of hydrogen-bonded polymer blends,
S.H. Zhang; R. Casalini; J. Runt; C.M. Roland, Macromolecules 36, 9917 (2003). [doi]

Role of strain crystallization in the fatigue resistance of double network elastomers,
P.G. Santangelo; C.M. Roland, Rubber Chem. Technol. 76, 892 (2003).

Segmental- and normal-mode dielectric relaxation of poly(propylene glycol) under pressure,
C.M. Roland; T. Psurek; S. Pawlus; M. Paluch, J. Polym. Sci. Pt. B-Polym. Phys. 41, 3047 (2003). [doi]

Effect of volume changes on segmental relaxation in siloxane polymers,
M. Paluch; R. Casalini; A. Patkowski; T. Pakula; C.M. Roland, Phys. Rev. E 68, 031802 (2003). [doi]

Does the arrhenius temperature dependence of the Johari-Goldstein relaxation persist above T-g?,
M. Paluch; C.M. Roland; S. Pawlus; J. Ziolo; K.L. Ngai, Phys. Rev. Lett. 91, 115701 (2003). [doi]

Electrostrictive behavior of poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene),
J.T. Garrett; C.M. Roland; A. Petchsuk; T.C. Chung, Appl. Phys. Lett. 83, 1190 (2003). [doi]

Dynamic properties of polyvinylmethylether near the glass transition,
R. Casalini; C.M. Roland, J. Chem. Phys. 119, 4052 (2003). [doi]

Strains in an inflated rubber sheet,
P.H. Mott; C.M. Roland; S.E. Hassan, Rubber Chem. Technol. 76, 326 (2003).

Pressure evolution of the excess wing in a type-B glass former,
R. Casalini; C.M. Roland, Phys. Rev. Lett. 91, 015702 (2003). [doi]

Chemical structure and local segmental dynamics in 1,2-polybutadiene,
C.M. Roland; R. Casalini; P. Santangelo; M. Sekula; J. Ziolo; M. Paluch, Macromolecules 36, 4954 (2003).

Correlation between configurational entropy and structural relaxation time in glass-forming liquids,
D. Prevosto; M. Lucchesi; S. Capaccioli; R. Casalini; P.A. Rolla, Phys. Rev. B 67, 174202 (2003). [doi]

Test of the Einstein-Debye relation in supercooled dibutylphthalate at pressures up to 1.4 GPa,
M. Paluch; M. Sekula; S. Pawlus; S.J. Rzoska; J. Ziolo; C.M. Roland, Phys. Rev. Lett. 90, 175702 (2003). [doi]

Influence of molecular structure on the dynamics of supercooled van der Waals liquids,
R. Casalini; M. Paluch; C.M. Roland, Phys. Rev. E 67, 031505 (2003). [doi]

Dynamics of salol at elevated pressure,
R. Casalini; M. Paluch; C.M. Roland, J. Phys. Chem. A 107, 2369 (2003). [doi]

Cohen-Grest model for the dynamics of supercooled liquids,
M. Paluch; R. Casalini; C.M. Roland, Phys. Rev. E 67, 021508 (2003). [doi]

Dynamic crossover in supercooled liquids induced by high pressure,
R. Casalini; M. Paluch; C.M. Roland, J. Chem. Phys. 118, 5701 (2003). [doi]

Temperature and volume effects on local segmental relaxation in poly(vinyl acetate),
C.M. Roland; R. Casalini, Macromolecules 36, 1361 (2003). [doi]

The relative contributions of temperature and volume to structural relaxation of van der Waals molecular liquids,
M. Paluch; C.M. Roland; R. Casalini; G. Meier; A. Patkowski, J. Chem. Phys. 118, 4578 (2003). [doi]

The Avramov model of structural relaxation,
M. Paluch; C.M. Roland, J. Non-Cryst. Solids 316, 413 (2003).

Pressure and temperature dependence of structural relaxation in diglycidylether of bisphenol A,
M. Paluch; C.M. Roland; J. Gapinski; A. Patkowski, J. Chem. Phys. 118, 3177 (2003). [doi]

Isochronal temperature-pressure superpositioning of the alpha-relaxation in type-A glass formers,
C.M. Roland; R. Casalini; M. Paluch, Chem. Phys. Lett. 367, 259 (2003).

2002 top

alpha-relaxation and the excess wing in polychlorinated biphenyls,
R. Casalini; C.M. Roland, Phys. Rev. B 66, 180201 (2002). [doi]

Dynamics of sorbitol at elevated pressure,
S. Hensel-Bielowka; M. Paluch; J. Ziolo; C.M. Roland, J. Phys. Chem. B 106, 12459 (2002). [doi]

Ionic conductivity and dielectric relaxation in poly[(phenyl glycidyl ether)-co-formaldehyde],
M. Paluch; T. Psurek; C.M. Roland, J. Phys.-Condes. Matter 14, 9489 (2002).

Near-constant loss and the loss from cooperative ion hopping in ionic conductors are not additive contributions,
K.L. Ngai; R. Casalini, Phys. Rev. B 66, 132205 (2002). [doi]

Correlation between the alpha relaxation and the excess wing for polychlorinated biphenyls and glycerol,
R. Casalini; M. Paluch; C.M. Roland, J. Therm. Anal. 69, 947 (2002).

Volume effects on the molecular mobility close to glass transition in supercooled phenylphthalein-dimethylether. II,
M. Paluch; R. Casalini; A. Best; A. Patkowski, J. Chem. Phys. 117, 7624 (2002). [doi]

Influence of the end groups on dynamics of propylene glycol oligomers studied by wideband dielectric spectroscopy,
S. Capaccioli; R. Casalini; M. Lucchesi; G. Lovicu; D. Prevosto; D. Pisignano; G. Romano; P.A. Rolla, J. Non-Cryst. Solids 307, 238 (2002).

Temperature and pressure behavior of the structural relaxation time in glass formers,
R. Casalini; S. Capaccioli; M. Lucchesi; M. Paluch; S. Corezzi; P.A. Rolla, J. Non-Cryst. Solids 307, 264 (2002).

Glass transition of an epoxy resin induced by temperature, pressure and chemical conversion: a rationale based on configurational entropy,
S. Corezzi; D. Fioretto; R. Casalini; P.A. Rolla, J. Non-Cryst. Solids 307, 281 (2002).

Effect of temperature on the terminal relaxation of branched polydimethysiloxane,
C.M. Roland; P.G. Santangelo, J. Non-Cryst. Solids 307, 835 (2002).

Pressure and temperature dependence of the alpha-relaxation in poly(methyltolylsiloxane),
M. Paluch; S. Pawlus; C.M. Roland, Macromolecules 35, 7338 (2002). [doi]

Electromechanical properties of poly(vinylidene fluoride-trifluoroethylene) networks,
R. Casalini; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 40, 1975 (2002). [doi]

Dynamics of aroclor and its modification by dissolved polystyrene,
R. Casalini; P.G. Santangelo; C.M. Roland, J. Chem. Phys. 117, 4585 (2002). [doi]

The effect of pressure on the structural and secondary relaxations in 1,1 '-bis (p-methoxyphenyl) cyclohexane,
S. Hensel-Bielowka; J. Ziolo; M. Paluch; C.M. Roland, J. Chem. Phys. 117, 2317 (2002). [doi]

Two crossover regions in the dynamics of glass forming epoxy resins,
S. Corezzi; M. Beiner; H. Huth; K. Schroter; S. Capaccioli; R. Casalini; D. Fioretto; E. Donth, J. Chem. Phys. 117, 2435 (2002). [doi]

Dielectric and mechanical relaxation of cresolphthalein-dimethylether,
M. Paluch; C.M. Roland; A. Best, J. Chem. Phys. 117, 1188 (2002). [doi]

Electrostrictive properties of poly(vinylidenefluoridetrifluoroethylene-chlorotrifluoroethylene),
G.S. Buckley; C.M. Roland; R. Casalini; A. Petchsuk; T.C. Chung, Chem. Mat. 14, 2590 (2002). [doi]

Temperature and pressure dependence of the alpha-relaxation in polymethylphenylsiloxane,
M. Paluch; C.M. Roland; S. Pawlus, J. Chem. Phys. 116, 10932 (2002). [doi]

Effect of pressure on the alpha relaxation in glycerol and xylitol,
M. Paluch; R. Casalini; S. Hensel-Bielowka; C.M. Roland, J. Chem. Phys. 116, 9839 (2002). [doi]

Pressure and temperature dependences of the dynamics of glass formers studied by broad-band dielectric spectroscopy,
S. Capaccioli; M. Lucchesi; R. Casalini; S. Presto; P.A. Rolla; M.T. Viciosa; S. Corezzi; D. Fioretto, Philos. Mag. B-Phys. Condens. Matter Stat. Mech. Electron. Opt. Magn. Prop. 82, 651 (2002). [doi]

Acoustic and dynamic mechanical properties of a polyurethane rubber,
P.H. Mott; C.M. Roland; R.D. Corsaro, J. Acoust. Soc. Am. 111, 1782 (2002). [doi]

Cation mass dependence of the nearly constant dielectric loss in alkali triborate glasses,
A. Rivera; A. Leon; C.P.E. Varsamis; A.D. Chryssikos; K.L. Ngai; C.M. Roland; L.J. Buckley, Phys. Rev. Lett. 88, 125902 (2002). [doi]

Segmental relaxation in end-linked poly(dimethylsiloxane) networks,
M.J. Schroeder; C.M. Roland, Macromolecules 35, 2676 (2002). [doi]

Nonlinear rheology of hyperbranched polyisobutylene,
C.G. Robertson; C.M. Roland; J.E. Puskas, J. Rheol. 46, 307 (2002).

Relation between structural relaxation time and configurational entropy: a test of the Adam-Gibbs model on epoxy resins,
S. Corezzi; D. Fioretto; S.C. Santucci; S. Capaccioli; R. Casalini; M. Lucchesi; E. Hempel; M. Beiner, Philos. Mag. B-Phys. Condens. Matter Stat. Mech. Electron. Opt. Magn. Prop. 82, 339 (2002).

2001 top

The fatigue life of Hevea and guayule rubbers,
P.G. Santangelo; C.M. Roland, Rubber Chem. Technol. 74, 69 (2001).

Aging of natural rubber in air and seawater,
P.H. Mott; C.M. Roland, Rubber Chem. Technol. 74, 79 (2001).

Dynamics near the glass temperature of low molecular weight cyclic polystyrene,
P.G. Santangelo; C.M. Roland; T. Chang; D. Cho; J. Roovers, Macromolecules 34, 9002 (2001). [doi]

Structural dependence of fast relaxation in glass-forming substances and correlation with the stretch exponent of the slow structural alpha-relaxation,
R. Casalini; K.L. Ngai, J. Non-Cryst. Solids 293, 318 (2001).

Effect of pressure on the dynamics of glass formers,
R. Casalini; S. Capaccioli; M. Lucchesi; P.A. Rolla; M. Paluch; S. Corezzi; D. Fioretto, Phys. Rev. E 64, 041504 (2001).

Highly electrostrictive poly(vinylidene fluoride-trifluoroethylene) networks,
R. Casalini; C.M. Roland, Appl. Phys. Lett. 79, 2627 (2001).

Elastomeric ozone concentration detector,
P.H. Mott; C.M. Roland, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process. 317, 65 (2001).

Temperature dependence of segmental and terminal relaxation in atactic polypropylene melts,
C.M. Roland; K.L. Ngai; P.G. Santangelo; X.H. Qiu; M.D. Ediger; D.J. Plazek, Macromolecules 34, 6159 (2001). [doi]

Influence of temperature, pressure and connectivity on the dynamics of a glass-forming system investigated by dielectric spectroscopy,
S. Corezzi; S. Capaccioli; R. Casalini; P. Rolla; G. Gallone, Macromol. Symp. 171, 253 (2001).

Glass transition of an epoxy resin - A wideband dielectric investigation,
S.C. Santucci; S. Corezzi; D. Fioretto; S. Capaccioli; R. Casalini; M. Lucchesi; S. Presto; P.A. Rolla, IEEE Trns. Dielectr. Electr. Insul. 8, 373 (2001).

Influence of temperature and pressure on the dynamics of glass formers explored by dielectric spectroscopy,
R. Casalini; S. Capaccioli; S. Presto; M. Lucchesi; P.A. Rolla; S. Corezzi; M. Paluch, IEEE Trns. Dielectr. Electr. Insul. 8, 395 (2001).

Effect of water inclusions on charge transport and polarization in porous media,
S. Capaccioli; M. Lucchesi; R. Casalini; P.A. Rolla; N. Bona, IEEE Trns. Dielectr. Electr. Insul. 8, 454 (2001).

Optical birefringence of polyisobutylene during creep and recovery,
P.H. Mott; A. Rizos; C.M. Roland, Macromolecules 34, 4476 (2001).

Study of the relaxation behaviour of a tri-epoxy compound in the supercooled and glassy state by broadband dielectric spectroscopy,
D. Pisignano; S. Capaccioli; R. Casalini; M. Lucchesi; P.A. Rolla; A. Justl; E. Rossler, J. Phys.-Condes. Matter 13, 4405 (2001).

Linear viscoelastic properties of hyperbranched polyisobutylene,
C.G. Robertson; C.M. Roland; C. Paulo; J.E. Puskas, J. Rheol. 45, 759 (2001).

Pressure dependence of structural relaxation time in terms of the Adam-Gibbs model,
R. Casalini; S. Capaccioli; M. Lucchesi; P.A. Rolla; S. Corezzi, Phys. Rev. E 63, 031207 (2001).

Interrupted shear flow of unentangled polystyrene melts,
P.G. Santangelo; C.M. Roland, J. Rheol. 45, 583 (2001).

Network structure in poly(vinylidene fluoride-trifluoroethylene) electrostrictive films,
G.S. Buckley; C.M. Roland, Appl. Phys. Lett. 78, 622 (2001).

2000 top

Crystallization of polydimethylsiloxane end-linked networks,
C.M. Roland; C.A. Aronson, Polym. Bull. 45, 439 (2000).

NMR study of the morphology of polystyrene linear/microgel blends,
K.J. McGrath; C.M. Roland; M. Antonietti, Macromolecules 33, 8354 (2000). [doi]

Comparison of glass formation kinetics and segmental relaxation in polymers,
C.G. Robertson; P.G. Santangelo; C.M. Roland, J. Non-Cryst. Solids 275, 153 (2000).

alpha- and beta-relaxations in neat and antiplasticized polybutadiene,
R. Casalini; K.L. Ngai; C.G. Robertson; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 38, 1841 (2000).

Application of impedance spectroscopy to the study of organic multilayer devices,
M.C. Petty; C. Pearson; A.P. Monkman; R. Casalini; S. Capaccioli; J. Nagel, Colloid Surf. A-Physicochem. Eng. Asp. 171, 159 (2000).

Mechanical and optical behavior of double network rubbers,
P.H. Mott; C.M. Roland, Macromolecules 33, 4132 (2000).

Influence of the wettability on the electrical response of microporous systems,
S. Capaccioli; M. Lucchesi; R. Casalini; P.A. Rolla; N. Bona, J. Phys. D-Appl. Phys. 33, 1036 (2000).

Check of the temperature- and pressure-dependent Cohen-Grest equation,
S. Corezzi; S. Capaccioli; R. Casalini; D. Fioretto; M. Paluch; P.A. Rolla, Chem. Phys. Lett. 320, 113 (2000).

Breadth of the alpha-relaxation function in 1,4-polybutadiene,
C.G. Robertson; C.M. Roland, Macromolecules 33, 1262 (2000).

1999 top

Ozone detection by crack-induced opacity in rubber,
P.H. Mott; C.M. Roland, Rubber Chem. Technol. 72, 769 (1999).

Organic vapour sensing using thin films of a co-ordination polymer: comparison of electrical and optical techniques,
R. Casalini; J.N. Wilde; J. Nagel; U. Oertel; M.C. Petty, Sens. Actuator B-Chem. 57, 28 (1999).

Creep of selenium near the glass temperature,
C.M. Roland; P.G. Santangelo; D.J. Plazek; K.M. Bernatz, J. Chem. Phys. 111, 9337 (1999).

The application of the energy landscape model to polymers,
C.M. Roland; P.G. Santangelo; K.L. Ngai, J. Chem. Phys. 111, 5593 (1999).

Segmental relaxation of poly(styrene-co-vinylphenol),
M.J. Schroeder; C.M. Roland; T.K. Kwei, Macromolecules 32, 6249 (1999).

Elasticity of polydiene networks in tension and compression,
C.M. Roland; P.H. Mott; G. Heinrich, Comput. Theor. Polym. Sci. 9, 197 (1999).

Response to "Comment on birefringence in the softening zone",
C.M. Roland; P.H. Mott, Macromolecules 32, 4728 (1999).

Sensitivity of the electrical admittance of a polysiloxane film to organic vapours,
R. Casalini; M. Kilitziraki; D. Wood; M.C. Petty, Sens. Actuator B-Chem. 56, 37 (1999).

Mechanical behavior of polystyrene microgels,
C.M. Roland; P.G. Santangelo; M. Antonietti; M. Neese, Macromolecules 32, 2283 (1999).

Rheology of star-branched polyisobutylene,
P.G. Santangelo; C.M. Roland; J.E. Puskas, Macromolecules 32, 1972 (1999).

Normal mode relaxation of polyisoprene in blends with vinyl polybutadienes,
M.J. Schroeder; C.M. Roland, Macromolecules 32, 2000 (1999).

1998 top

Test of the energy landscape interpretation of fragility in polymers,
P.G. Santangelo; C.M. Roland, Phys. Rev. B 58, 14121 (1998).

The effect of organic vapours on the permittivity of a co-ordination polymer Langmuir-Blodgett film,
R. Casalini; J. Nagel; U. Oertel; M.C. Petty, J. Phys. D-Appl. Phys. 31, 3146 (1998).

Birefringence of polymers in the softening zone,
P.H. Mott; C.M. Roland, Macromolecules 31, 7095 (1998).

Effect of long-chain branching on the rheology of 1,4-polyisoprene,
P.G. Santangelo; C.M. Roland, J. Non-Cryst. Solids 235, 709 (1998).

Molecular weight dependence of fragility in polystyrene,
P.G. Santangelo; C.M. Roland, Macromolecules 31, 4581 (1998).

The electrical behaviour of multilayer polypyrrole films,
R. Casalini; L.M. Goldenberg; C. Pearson; B.K. Tanner; M.C. Petty, J. Phys. D-Appl. Phys. 31, 1504 (1998).

Comment on "Nonaffine deformation and elasticity of polymer networks",
C.M. Roland; P.H. Mott, Macromolecules 31, 4033 (1998).

Temperature dependence of mechanical and dielectric relaxation in cis-1,4-polyisoprene,
P.G. Santangelo; C.M. Roland, Macromolecules 31, 3715 (1998).

The coupling model approach to the terminal relaxation,
P.G. Santangelo; K.L. Ngai; C.M. Roland, Polymer 39, 681 (1998).

Intrinsic defect effects on NR permeability,
C.M. Roland; I.S. Choi; M.J. Schroeder, Rubber & Plastics News January 12, 14 (1998).

1997 top

The viscoelastic behaviour of networks,
C.M. Roland; K.L. Ngai; D.J. Plazek, Comput. Theor. Polym. Sci. 7, 133 (1997).

An electrical impedance study of Langmuir-Blodgett films containing a tetrabutylammonium Ni(dmit)(2) complex,
R. Casalini; L.M. Goldenberg; C. Pearson; M.R. Bryce; M.C. Petty, J. Phys. D-Appl. Phys. 30, 2928 (1997).

Strain-crystallization of guayule and hevea rubbers,
I.S. Choi; C.M. Roland, Rubber Chem. Technol. 70, 202 (1997).

Structural relaxation dynamics of ortho-terphenyl,
C.M. Roland; K.L. Ngai, Mech. Time Dep. Mat. 66, 109 (1997).

Influence of the glass transition on the secondary relaxation of an epoxy resin,
R. Casalini; D. Fioretto; A. Livi; M. Lucchesi; P.A. Rolla, Phys. Rev. B 56, 3016 (1997).

Dielectric parameters to monitor the crosslink of epoxy resins,
R. Casalini; S. Corezzi; A. Livi; G. Levita; P.A. Rolla, J. Appl. Polym. Sci. 65, 17 (1997).

Short-time relaxational dynamics of the ''strong'' glass-former methanol,
K.L. Ngai; C.M. Roland, J. Phys. Chem. B 101, 4437 (1997).

Commentary on 'Strong and fragile liquids - A brief critique',
C.M. Roland; K.L. Ngai, J. Non-Cryst. Solids 212, 74 (1997).

''Fast dynamics of glass-forming glycerol'' - Comment,
K.L. Ngai; C.M. Roland, Phys. Rev. E 55, 2069 (1997).

Reversible optical data storage on poly(ethylene terephthalate),
G.S. Buckley; C.M. Roland, Polym. Eng. Sci. 37, 138 (1997).

Short-time viscous and density relaxation in glycerol and ortho-terphenyl,
C.M. Roland; K.L. Ngai, J. Chem. Phys. 106, 1187 (1997).

1996 top

''Depolarized light scattering study of molten zinc chloride'' - Comment
K.L. Ngai; C.M. Roland, Phys. Rev. E 54, 6969 (1996).

Birefringence of rubber during creep and recovery
P.H. Mott; C.M. Roland, Macromolecules 29, 8492 (1996).

Intrinsic defects and the failure properties of cis-1,4-polyisoprenes
I.S. Choi; C.M. Roland, Rubber Chem. Technol. 69, 591 (1996).

Normal mode relaxation in linear and branched polyisoprene
C.M. Roland; C.A. Bero, Macromolecules 29, 7521 (1996).

Elasticity of natural rubber networks
P.H. Mott; C.M. Roland, Macromolecules 29, 6941 (1996).

Segmental relaxation in poly(dimethylsiloxane)
C.M. Roland; K.L. Nagi, Macromolecules 29, 5747 (1996).

Unified dielectric description of the dynamics of polymeric systems undergoing either thermal or chemical vitrification
R. Casalini; S. Corezzi; D. Fioretto; A. Livi; P.A. Rolla, Chem. Phys. Lett. 258, 470 (1996).

Short time dynamics of glass-forming liquids - Reply
C.M. Roland; K.L. Ngai, J. Chem. Phys. 104, 8171 (1996).

Temperature dependence of relaxation in polypropylene and poly(ethylene-co-propylene)
P.G. Santangelo; K.L. Ngai; C.M. Roland, Macromolecules 29, 3651 (1996).

Terminal relaxations in linear and three-arm star polyisoprenes
C.A. Bero; C.M. Roland, Macromolecules 29, 1562 (1996).

The anomalous Debye-Waller factor and the fragility of glasses
C.M. Roland; K.L. Ngai, J. Chem. Phys. 104, 2967 (1996).

Self-similarity of dielectric relaxation and conductivity in cross-linking systems
R. Casalini; A. Livi; P.A. Rolla; G. Levita; D. Fioretto, Phys. Rev. B 53, 564 (1996).

1995 top

Uniaxial Deformation of Rubber Cylinders,
P.H. Mott; C.M. Roland, Rubber Chem. Technol. 68, 739 (1995).

Viscoelastic Properties of Polymers: 4. Thermorheological Complexity of the Softening Dispersion in Polyisobutylene,
D.J. Plazek; I.C. Chay; K.L. Ngai; C.M. Roland, Macromolecules 28, 6432 (1995).

High Frequency Relaxation of o-Terphenyl,
C.M. Roland; K.L. Ngai; L.J. Lewis, J. Chem. Phys. 103, 4632 (1995).

Reaction Field Model with Free Volume for the NMR Chemical Shift of Xe-129 Dissolved in Organic Solvents,
J.H. Walton; J.B. Miller; C.M. Roland, Appl. Magn. Reson. 8, 535 (1995).

Short-time Dynamics of Glass-Forming Liquids,
C.M. Roland; K.L. Ngai, J. Chem. Phys. 103, 1152 (1995).

Component Dynamics in Polyisoprene/Poly(vinylethylene) Blends,
K.L. Ngai; C.M. Roland, Macromolecules 28, 4033 (1995).

Failure Properties of Natural Rubber Double Networks,
P.G. Santangelo; C.M. Roland, Rubber Chem. Technol. 68, 124 (1995).

A Comparison of Segmental Dynamics in Polymers by Solid-state C-13 NMR Spectroscopy,
K.J. McGrath; K.L. Ngai; C.M. Roland, Macromolecules 28, 2825 (1995).

C-13 NMR Study of Component Dynamics in Aroclor/Poly(vinylethylene) Mixtures,
K.J. McGrath; C.M. Roland, Macromolecules 28, 2982 (1995).

1994 top

Proton NMR Determination of Crystallinity in Poly(ethylene-terephthalate),
C.M. Roland; J.H. Walton; J.B. Miller, Magn. Reson. Chem. 32, S36 (1994).

An Elastomeric Ejection System,
I.S. Choi; C.M. Roland; L.C. Bissonnette, Rubber Chem. Technol. 67, 892 (1994).

NMR Study of Miscibility in Polyepichlorohydrin Poly(vinylmethylether) Blends,
K.J. McGrath; C.M. Roland, Rubber Chem. Technol. 67, 629 (1994).

Constraint Dynamics and Chemical Structure,
C.M. Roland; K.L. Ngai, J. Non-Cryst. Solids 172-174, 868 (1994).

Concentration Fluctuations and Dynamic Heterogeneity in Pip/pve Blends,
K.J. McGrath; C.M. Roland, J. Non-Cryst. Solids 172-174, 891 (1994).

Miscibility in Poly(vinylethylene)/Poly(isoprene) Blends,
K.J. McGrath; J.B. Miller; C.M. Roland, J. Non-Cryst. Solids 172-174, 897 (1994).

Dielectric and Mechanical Relaxation in PMPS, BMC and Their Mixtures,
P.G. Santangelo; C.M. Roland; K.L. Ngai; A.K. Rizos; H. Katerinopoulos, J. Non-Cryst. Solids 172-174, 1084 (1994).

The Use of the Transfer-function in Dielectric Measurements by Time-domain Reflectometry,
R. Casalini; A. Livi; P.A. Rolla, Jpn. J. Appl. Phys. Part 2 - Lett. 33, L1271 (1994).

Segmental Relaxation in Blends of Polychloroprene and Epoxidized Polyisoprene,
C.M. Roland; P.G. Santangelo; Z. Baram; J. Runt, Macromolecules 27, 5382 (1994).

Observation of the Component Dynamics in a Miscible Polymer Blend by Dielectric and Mechanical Spectroscopies,
A. Alegria; J. Colmenero; K.L. Ngai; C.M. Roland, Macromolecules 27, 4486 (1994).

Anomalous Relaxation in Polychlorinated Biphenyl Polybutadiene Mixtures,
P.G. Santangelo; K.L. Ngai; C.M. Roland, Macromolecules 27, 3859 (1994).

The Mechanical Behavior of Double Network Elastomers,
P.G. Santangelo; C.M. Roland, Rubber Chem. Technol. 67, 359 (1994).

Junction Dynamics and the Elasticity of Networks,
K.L. Ngai; C.M. Roland, Macromolecules 27, 2454 (1994).

Detailed Correspondences Between Dielectric and Mechanical Relaxations in Poly(vinylethylene),
J. Colmenero; A. Alegria; P.G. Santangelo; K.L. Ngai; C.M. Roland, Macromolecules 27, 407 (1994).

1993 top

A Constraint Dynamics Approach to Rubber Elasticity,
K.L. Ngai; C.M. Roland; A.F. Yee, Rubber Chem. Technol. 66, 817 (1993).

Chemical Sstructure and Intermolecular Cooperativity - Dielectric Relaxation Results,
K.L. Ngai; C.M. Roland, Macromolecules 26, 6824 (1993).

Plateau Modulus of Epoxidized Polybutadiene,
C.M. Roland; J.K. Kallitsis; K.G. Gravalos, Macromolecules 26, 6474 (1993).

Relaxation Dynamics in Poly(methylphenylsiloxane), 1,1-bis(p-methoxyphenyl)cyclohexane, and Their Mixtures,
C.M. Roland; P.G. Santangelo; K.L. Ngai; G. Meier, Macromolecules 26, 6164 (1993).

Chain Configuration of Polystyrene Arising From Freeze-Drying Dilute Solutions,
K.J. McGrath; C.M. Roland; R.G. Weiss, Macromolecules 26, 6127 (1993).

The NMR Chemical-shift of Xe-129 Dissolved in Polymers,
J.B. Miller; J.H. Walton; C.M. Roland, Macromolecules 26, 5602 (1993).

Origin of the Negative Excess Enthalpy in Poly(vinylethylene) cis-1,4-Polyisoprene Blends,
C.M. Roland; J.B. Miller; K.J. McGrath, Macromolecules 26, 4967 (1993).

Transverse Heterogeneity in Pet Fibers,
D.W. Tomlin; C.M. Roland; L.I. Slutsker, J. Polym. Sci. Pt. B-Polym. Phys. 31, 1331 (1993).

The Amorphous Phase in High-Speed Spun Pet Fibers,
K.L. Peng; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 31, 1339 (1993).

Phase Transitions in Polymer Blends via Xe-129 NMR Spectroscopy,
J.H. Walton; J.B. Miller; C.M. Roland; J.B. Nagode, Macromolecules 26, 4052 (1993).

Lattice Expansion During Polyisoprene Crystallization From Blends,
D.W. Tomlin; C.M. Roland, Polymer 34, 2665 (1993).

Distinctive Manifestations of Segmental Motion in Amorphous Poly(tetrahydrofuran) and Polyisobutylene,
P.G. Santangelo; K.L. Ngai; C.M. Roland, Macromolecules 26, 2682 (1993).

The Barrier Performance of Latex Rubber,
C.M. Roland, Rubber World 208, 15 (1993).

1992 top

Chain Ends and the Mullins Effect in Rubber
P.G. Santangelo; C.M. Roland, Rubber Chem. Technol. 65, 965 (1992).

Terminal and Segmental Relaxations in Epoxidized Polyisoprene
C.M. Roland, Macromolecules 25, 7031 (1992).

Segmental Relaxation in Miscible Polymer Blends
C.M. Roland; K.L. Ngai, J. Rheol. 36, 1691 (1992).

Orientational Correlations in Polyisoprene Poly(vinylethylene) Mixtures
I.S. Zemel; C.M. Roland, Polymer 33, 4522 (1992).

Normalization of the Temperature Dependence of Segmental Relaxation Times
C.M. Roland; K.L. Ngai, Macromolecules 25, 5765 (1992).

Temperature Dependence of Segmental Motion in Polyisobutylene and Poly(vinylethylene)
K.J. McGrath; K.L. Ngai; C.M. Roland, Macromolecules 25, 4911 (1992).

Trends in the Temperature Dependency of Segmental Relaxation in TMPC PS Blends
K.L. Ngai; C.M. Roland; J.M. Oreilly; J.S. Sedita, Macromolecules 25, 3906 (1992).

Negative Excess Enthalpy in a van der Waals Polymer Mixture
D.W. Tomlin; C.M. Roland, Macromolecules 25, 2994 (1992).

Xe-129 NMR as a Probe of Polymer Blends
J.H. Walton; J.B. Miller; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 30, 527 (1992).

NMR Study of Chain Interactions in Freeze-Dried Polystyrene Solutions
K.J. McGrath; C.M. Roland, Macromolecules 25, 1366 (1992).

Miscibility in Poly(vinylethylene) Isotopic Mixtures by C-13 Nmr
K.J. McGrath; C.M. Roland, Macromolecules 25, 166 (1992).

1991 top

Electrical Conductivity in Rubber Double Networks
C.M. Roland; K.L. Peng, Rubber Chem. Technol. 64, 790 (1991).

Segmental Relaxation and Molecular Structure in Polybutadienes and Polyisoprene
C.M. Roland; K.L. Ngai, Macromolecules 24, 5315 (1991).

High Temperature Crystallization of Poly(ethylene-terephthalate)
C.M. Roland, Polym. Eng. Sci. 31, 849 (1991).

Thermal Crystallization of Polytetrahydrofuran Networks
C.M. Roland; G.S. Buckley, Rubber Chem. Technol. 64, 74 (1991).

Dynamic Heterogeneity in a Miscible Polymer Blend
C.M. Roland; K.L. Ngai, Macromolecules 24, 2261 (1991).

Intersegmental Interaction and Critical Concentrations in Pet-HFIP Solutions
M.F. Sonnenschein; C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 29, 431 (1991).

Miscible Mixtures of Polychloroprene and Epoxidized Polyisoprene
J.B. Nagode; C.M. Roland, Polymer 32, 505 (1991).

1990 top

Interaggregate Interaction in Filled Rubber,
C.M. Roland; G.F. Lee, Rubber Chem. Technol. 63, 554 (1990).

Orientation Effects in Rubber Double Networks,
C.M. Roland; M.L. Warzel, Rubber Chem. Technol. 63, 285 (1990).

Absorption and Fluorescence Spectra of Poly(ethylene-terephthalate) Dimers,
M.F. Sonnenschein; C.M. Roland, Polymer 31, 2023 (1990).

Nuclear Magnetic Resonance Study of Polyisoprene Poly(vinylethylene) Miscible Blends,
J.B. Miller; K.J. McGrath; C.M. Roland; C.A. Trask; A.N. Garroway, Macromolecules 23, 4543 (1990).

Poly(ethylene-terephthalate) Crystallization as a Method for Microlithography,
M.F. Sonnenschein; A.M. Kotliar; C.M. Roland, Polym. Eng. Sci. 30, 1165 (1990).

Synthetic Sequence Effects in Polyurethane Poly(n-butyl methacrylate) Mixtures - Grafting and Mechanical Properties,
R.B. Fox; J.P. Armistead; C.M. Roland; D.J. Moonay, J. Appl. Polym. Sci. 41, 1281 (1990).

High Resolution Ablation of Amorphous Polymers Using CO2 Laser Irradiation,
M.F. Sonnenschein; C.M. Roland, Appl. Phys. Lett. 57, 425 (1990).

1989 top

Network Recovery From Uniaxial Extension: 1. Elastic Equilibrium,
C.M. Roland, Rubber Chem. Technol. 62, 863 (1989).

Miscible Elastomer Mixtures,
C.M. Roland; C.A. Trask, Rubber Chem. Technol. 62, 896 (1989).

Anomalous Fatigue Behavior in Polyisoprene,
C.M. Roland; J.W. Sobieski, Rubber Chem. Technol. 62, 683 (1989).

Rubber Mixtures,
C.M. Roland, Rubber Chem. Technol. 62, 456 (1989).

The Mullins Effect in Crosslinked Rubber,
C.M. Roland, J. Rheol. 33, 659 (1989).

A Nearly Ideal Mixture of High Polymers,
C.A. Trask; C.M. Roland, Macromolecules 22, 256 (1989).

1988 top

Interactions in a Miscible Polymer Blend,
C.M. Roland, Rubber Chem. Technol. 61, 866 (1988).

Miscibility Limits in Poly(vinylethylene) Isotopic Mixtures,
C.M. Roland; C.A. Trask, Polym. Bull. 20, 471 (1988).

Improved Dispersive Mixing Through Reduction in Flow Field Vorticity,
C.M. Roland; M. Nguyen, J. Appl. Polym. Sci. 35, 2141 (1988).

Rheology of a Miscible Polymer Blend,
C.M. Roland, J. Polym. Sci. Pt. B-Polym. Phys. 26, 839 (1988).

1987 top

1985 top

Defect Accumulation in Rubber,
C.M. Roland; C.R. Smith, Rubber Chem. Technol. 58, 806 (1985).

Macromolecular Diffusion and the Autoadhesion of Polybutadiene,
C.M. Roland; G.G.A. Bohm, Macromolecules 18, 1310 (1985).

The Structure of Azoester-modified Polybutadiene Elastomers,
C.M. Roland; G.G.A. Bohm; P. Sadhukhan, J. Appl. Polym. Sci. 30, 2021 (1985).

1984 top

The Mechanism for Enhanced Autoadhesion in Azoester-Modified Polybutadienes,
C.M. Roland; G.G.A. Bohm, J. Appl. Polym. Sci. 29, 3803 (1984).

1981 top

Rotation-Vibration CARS Spectra of the 2-nu-2 Mode in CO2 Gas,
C.M. Roland; W.A. Steele, J. Chem. Phys. 74, 2733 (1981).

1980 top

Intensities in Pure Rotational CARS of Air,
C.M. Roland; W.A. Steele, J. Chem. Phys. 73, 5919 (1980).

Band Shapes in CARS - Background Effects and Overlapping Resonances,
C.M. Roland; W.A. Steele, J. Chem. Phys. 73, 5924 (1980).